Table of Contents
In this article, we were discussing the Carnot cycle, Carnot cycle efficiency, and other related terms for the Carnot heat engine.Â
This article is quite long, but you should have a complete understanding of the terms which were used later in the Carnot cycle.
Let us begin…..
Terms used in Carnot cycle – A look-up
1. Laws of thermodynamics that are involved in the Carnot cycle. |
2. What are the Spontaneous and Non-spontaneous processes? |
3. What are the Reversible and irreversible processes? |
4. what is the heat engine? |
5. Heat engine efficiency. |
6. What is a Carnot heat engine and a Carnot cycle? |
7. Complete Carnot cycle processes with diagrams and derivations. |
8. Carnot cycle PV diagram. |
9. Carnot heat engine efficiency with examples. |
10. Carnot theorem. |
11. The refrigerator as a reversed Carnot cycle. |
12. Co-efficient of performance. |
13. Entropy and Carnot cycle. |
14. Carnot cycle TS diagram. |
As you know, thermodynamics is the branch of science which deals with the study of the conversion of heat energy into other forms of energy and gives information about this conversion quantitatively.
Isothermal process – Carnot CycleÂ
In thermodynamics, if the temperature change in a thermodynamics process is constant, then the process is called an isothermal process.
As in Carnot heat engine, ideal gas as a working substance is used, then for an ideal gas isothermal process,
PV = Constant
Here P is the pressure of the gas,
V is the volume of the gas and,
the temperature T is constant.
Adiabatic process
In a thermodynamical system, no heat transfer from the system to the surrounding or from surrounding to the system means all heat contained in the system remains constant.
If any work is done in the adiabatic process, then this can only happen when the system’s internal energy (U) changed.
For an ideal gas,
P(V)γ = ConstantÂ
Here Gamma (γ)is the ratio of two specific heats of the gas at constant volume and constant pressure.
Laws of thermodynamics
Carnot heat engine obeys the first law and also the second law of thermodynamics.
While the Carnot cycle laid the foundation of the second law of thermodynamics.
let us discuss these laws.
The first law of thermodynamics
According to the first law of thermodynamics, if a certain amount of work is done, an equivalent amount of heat is produced and if a certain amount of heat is absorbed, an equivalent amount of work is done.
It means W = Q or Q = W
Q is the heat and W is the work done.
The First law of thermodynamics is also the law of conservations of energy.
Law of conservation of energy
Energy can neither be created nor be destroyed.
On behalf of this law, you can say that whole energy in the universe is conserved.
These conversions of energies are interconvertible.
The second law of thermodynamics
Many statements are given by scientists for the 2nd law of thermodynamics. Such as the statement by Lord Kelvin, Clausius, Planck-Kelvin, etc.
In thermodynamics, it was seen later that, all these statements are equivalent to each other.
Kelvin Planck’s statement for the second law of thermodynamics
It is impossible to construct a heat engine operating in cycles, which extract heat from a single thermal reservoir and converts the whole of it into work.
The second law is the most fundamental law of nature.
The limitations of the first law encouraged scientists to find the second law of thermodynamics.
As you know the first law only tells us the conversion of energies into other forms of energy.
But this law did not give information about the quantity and direction-flow of conversions and many other reverse parameters.
You can say the second law of thermodynamics is the law of nature.
Spontaneous and Non-spontaneous
Before you moved to the Carnot cycle, you should know about the spontaneous and non-spontaneous processes?
Carnot heat engine and all other heat engines follow the second law of thermodynamics.
The second law of thermodynamics is correlated with the spontaneous and non-spontaneous processes.
In a simple way, you can say that by the study of 2nd law you may tell more about the spontaneous and non-spontaneous process.
Spontaneous process
A spontaneous process, which has a tendency to do occur by itself in nature means no need for input energy from outside sources.
Also, a process is spontaneous if some initial effort is done and sometimes it is conditional.
For example
waterfalls (water itself falls from upper to lower surface) or if we move a ball on an inclined plane from top to bottom,
Iron rust, mixing sugar in water,
Melting of ice at different conditions,
The process of changing diamond into graphite at certain conditions, the process of decay of radioactive isotopes, etc.
In these examples some of the processes happen only by themselves, Such as waterfalls, mixing of sugar in water, a ball rolling top to down, etc.
These processes are naturally occurring and also condition-based.
If we move water with a spoon, the mixing rate of sugar is more than by itself.
Similarly in salt.
In the case of a ball, if we give a little push to the ball, after then the ball start continues to rolling itself on the inclined plane from top to down.
Non-spontaneous process
If we reverse the spontaneous process, which is not possible by itself, then it called a non-spontaneous process.
These processes need external effort in the form of energy or work.
Example
The water does not move by itself from down to top.
You need a water pump to continue this process.
Reversible and Irreversible process
A Carnot heat engine can work in a reverse direction, so here, we take a short view of reversible and irreversible processes.
Reversible process
A process is reversible if the system and surroundings came back to their original state in the opposite direction, after passing through the same intermediate conditions as during the direct process.
There are infinitesimal changes during the reversible process.
A reversible process can take an infinite amount of time to complete.
In actual practice, a perfect reversible process is impossible.
Examples
Some processes can be considered as a reversible process,
such as an isothermal expansion and compression in the case of an ideal gas at a constant temperature in a cyclic process.
If we compress a spring at a slow rate, then the work done by spring during expansion is equal to the applied work during compression.
Irreversible process
Any process, which is not reversible is called an irreversible process.
Examples
There are lots of examples of irreversible processes.
Some of these are,
- Transfer of heat by radiation.
- The heat produced during the current flow through a resistance.
- The heat produced during relative motion with friction.
- Throttling
- The plastic deformation
- Diffusion, etc.
Now you understood a few concepts and terms used in heat engines or Carnot cycle.
Let us talk about the heat engine and the Carnot heat engine process, by keeping these terms in mind.
What is a heat engine?
A heat engine is a device or machine, which converts heat energy into useful work.
Heat engine examples
The internal combustion engine,
The thermal power plant,
A steam locomotive engine, etc.
Heat engine construction and working
In a heat engine, a source (Heat reservoir) is used to transfer heat to Engine (E)at high-temperature T1.
Let Q1Â be the heat absorbed by the engine from the source.
Work is performed by the heat engine = W
According to the second law of thermodynamics,
“All work can be converted into heat, but all heat can not be converted into work”
It means some amount of heat is always lost.
Let the heat loss is equal to Q2.
Therefore work done is, W = Q1-Q2Â
To full fill, this requirement a sink (Heat reservoir) at low-temperature T2 is used in a heat engine.
As you know heat engines obey both the first law of thermodynamics and the second law of thermodynamics.
From the above figure, it is clear that a heat engine is a device, which converts heat into work.
The term “law of conversation of energy” is not violated by heat engines.
On another hand, we can say that the heat engine obeys the first law of thermodynamics.
According to the first law of thermodynamics, conversions of energies are interconvertible.
Hence, W = Q ⇒ Work is done = Heat produced.
According to the Clausius, the derivation of the first law,
As in heat engines, the working is a cyclic process, therefore,
internal energy change (ΔU) = 0
This is because for a cyclic process change in internal energy (ΔU) is always Zero (0).
Hence proved, Q = WÂ Â
Heat engine efficiency
The efficiency of a heat engine is the ratio of output mechanical energy to the input heat energy.
The efficiency of heat engines is denoted by a symbol named as, eta = η
The formula of heat engine efficiency (η) = W/Q1
Here W = output mechanical work during the complete cycle.
Q1 = Heat absorbing from the source at a high temp during the complete cycle.
As we know W = Q ⇒  Q1-Q2Â
after using this, η = Q1−Q2/Q1
What is a Carnot heat engine?
The Carnot heat engine is a hypothetical heat engine, which is given by A French mechanical engineer Nicolas Léonard Sadi Carnot.
He was a physicist, military scientist in the French army.
The Carnot Sadi was born on 1 June 1796 and died at the age of 36 years on 24 August 1832 in France.
He published a book at the age of 27 years in 1824 named “Reflections on the Motive Power of Fire”.
The Carnot heat engine is a reversible heat engine working between cycles of operations.
So, in the Carnot heat engine, the ideal gas, which is used as a working substance comes back to its initial state at the end of each cycle.
What is the Carnot cycle?
The Carnot heat engine works on the four reversible processes.
Isothermal gas expansion
Adiabatic gas expansion
Isothermal gas compression
Adiabatic gas compression
In the Carnot heat engine, the working series of these four processes is called the Carnot cycle.
The Carnot cycle construction
As you know that the Carnot heat engine works on the four operations, called cycle.
In the making of this type of cycle, the Sadi Carnot uses two different heat reservoir (Source and sink) at different temperature range, T1 and T2.Â
A cylinder, a piston, and also an insulating stand.
Let us talk about these requirements in detail.
♦ CylinderÂ
A cylinder that has perfectly non-conducting walls and the base of the cylinder is perfectly conducting.
A frictionless, weightless, and Perfectly Non-conducting piston is used to fit inside the cylinder.Â
An ideal gas is used in the cylinder as a working substance.
♦ Source
It is an infinite thermal capacity heat reservoir at a fixed high-temperature T1.
Infinite thermal capacity means during adding and subtracting of heat from the reservoir does not change its temperature T1.
♦ Sink
It is a second heat reservoir, which has also infinite heat capacity at a fixed low-temperature T2.
♦ Perfectly Non-Conducting stand
A perfectly Non-Conducting stand is used during operations in the Carnot cycle process.Â
Carnot cycle PV diagram
The processes during the Carnot cycle and total work done can be shown by the PV diagram.
In this pressure and volume graph, change in pressure shown vertically, and change in volume shown horizontally directions.
This Carnot cycle PV diagram shows all four reversible processes and their changing values.
The total area ABCDA inclosed by the PV diagram is the work done during a complete Carnot cycle.
Carnot cycle working
For changing the pressure during four processes, some weights were added on the piston and some weight removed from the piston.
1 Reversible Isothermal expansion
In this process, the cylinder is placed on the source.
As the base of the cylinder is perfectly conducting, then let Q1 be the heat absorbed from the source at a temperature of T1 by the gas.Â
Now slowly remove the weight.
Due to this gas expand at a constant temperature T1, as a result, the volume increases and the pressure decreases.
As you know, if the gas is expanding slowly at a constant temperature and the pressure-volume changes then the process is an isothermal expansion.
In this process, work W is done by the gas on the surroundings is equal to QÂ heat absorbed from the source.
Let in the initial state the gas has P1, V1, T1 are the respectively the pressure, volume, and temperature.
See in the PV diagram
After expansion, the pressure decreases from P1 to P2, the volume increases from V1 to V2, and the temperature remains constant at T1.
The work doneÂ
W = Q − ΔU
But in this process, internal energy (U) is not changing, as the temperature is constant, the work is done only due to heat absorbed.
The internal energy is temperature-dependent.
Therefore, the change in internal energy (ΔU) is equal to zero (0).
W = Q − 0 ⇒ W = Q
As we are in the first process of the cycle then,
ΔU = 0 can be denoted by ΔU1 = 0
W1 = Q1 ⇒ Work done for curve AB on the PV diagram.
Now applying the work done formula for the Isothermal process in the ideal gas case.
Which is W = nRT loge V2/V1Â
(Where n = no. of moles of gas, R is gas constant, and V2, V1 are volume changes and T is the temperature).
Hence, W1 = Q1 =nRT1 loge V2/V1Â Â Â (For first process temperature T is T1)
This is the work done in the first process.
2 Reversible Adiabatic Expansion
In this process, the cylinder removed from the source and placed on the perfectly Non-conducting stand.
As the stand is perfectly non-conducting, no heat transfer takes place during this process.
Now remove the weight fast and gas start expanding.
Now the work is done due to a decrease in internal energy (U) of gas and because of it, the temperature starts falling.
As you know, if the gas expanding and no heat transfer takes place from the system to the surrounding or from the surrounding to the system, then the process is an adiabatic expansion.
Removing of weight is until we reach to the sink’s temperature, which is T2.
Let, due to a decrease in internal energy (U) the temperature falls from T1 to T2 equal to sink temperature.
The volume and pressure also change, volume increases from V2 to V3 and pressure decreases from P2 to P3.
The work doneÂ
W = Q − ΔU,
W = 0 − ΔU ⇒ W = −ΔU,    (Q = 0, as no heat transfer)
As we are in the second process of the cycle then,
W2 = −ΔU2 ⇒ Work done for curve BC on the PV diagram.
The Work done formula in terms of internal energy change for an adiabatic process in the ideal gas case.
W = −nR (T2−T1)/1−γ
Here ΔU = nCvΔT ⇒ nR (Tlow−Thigh)
For ideal gas case ⇒ nR (T2−T1)/1−γ
In term of the second process, the work done is,
W2 = −ΔU2 ⇒ −nR (T2−T1)/1−γ
This is the work done in the second process.
3 Reversible Isothermal Compression
In this process, the cylinder removed from the stand and placed on the sink.
Some weights were added on the piston.
In this process, the temperature (T2) of the gas inside the cylinder is the same as the temperature (T2) of the sink.
It means no temperature change during the process, hence temperature is constant.
The work is done in the form of heat rejected to the sink.
Let Q2 be the heat rejected to the sink at constant temperature T2Â as the base of the cylinder is conducting.
During this process, the volume starts to decrease from V3 to V4 and the pressure starts to increase from P3 to P4.
We know that if the gas compress at a constant temperature and the value of its pressure and volume changes then the process is Isothermal compression.
As the temperature is constant then there is no change in internal energy (U).
The work done
W = Q − ΔU ⇒ W = Q − 0 ⇒ W = Q  (As the ΔU is equal to Zero)
As we are in the third process of the cycle then,
ΔU = 0 can be denoted by ΔU3 = 0
W3 = Q2 ⇒ nRT2 loge V4/V3
W3 = nRT2 loge V4/V3 ⇒ Work done for curve CD on the PV diagram.
This is the work done for the third process.
4 Reversible Adiabatic Compression
In this process, the cylinder removed from the sink and placed again on the stand.
Weights are added on the piston.
The work is done during this process is due to an increase in the internal energy (U) of gas and because of it, the temperature starts increasing.
Let the temperature change from T2 to T1, which is the same as the initial state of the gas.
As the stand is perfectly Non-conducting, no heat transfer takes place during this process.
As you know, if the gas compress and no heat transfer takes place from the system to the surrounding or from surrounding to the system, then the process is an adiabatic compression.
In this process, the volume decreases from V4 to V1, and respectively the pressure increases from P4 to P1, and the gas comes back to its initial state.
The work done
W = Q − ΔU,
W = 0 − ΔU ⇒ W = −ΔU    (Q = 0, as no heat transfer)
As we in the fourth process of the cycle then,
W4 = −ΔU4 ⇒ Work done for curve DA on the PV diagram.
Here temperature changes from T2 to T1 then,
W4 = −nR (T1−T2)/1−γ
Here ΔU = nCvΔT ⇒ nR(Thigh−Tlow), Â
W4 = −ΔU4 ⇒ −nR(T1−T2)/1−γ
This is the work done by the fourth process of the cycle.
Total work done by the Carnot cycle.Â
When you study the PV diagram of the Carnot heat engine, you see, that the total
area enclosed by the PV diagram is equal to the total work done by the Carnot cycle.
Now the total area enclosed by the PV diagram = Area ABCDA.
The total work done by the Carnot cycle = W
W = W1 + W2 + W3 + W4
Now adding the terms,
W1 = nRT1 loge V2/V1
W2 = −nR (T2−T1)/1−γ
W3 =Â nRT2 loge V4/V3
W4 = −nR (T1−T2)/1−γ
Here W2 + W4Â = 0Â Â (After solving)
Hence W = w1 + W3
W = nRT1logeV2/V1 − nRT2logeV3/V4  (After solving)
After solving the curves AB, BC, CD, DA in terms of isothermal and adiabatic processes, we get,
V2/V1 = V3/V4
Substitute this, W = nRT1logeV2/V1 − nRT2logeV2/V1Â
Hence total work done by the carnot cycle W = nRlogeV2/V1[T1−T2]
In this complete cycle net amount of heat absorbed Q = Q1-Q2
Hence from the first law of thermodynamics, W = Q
Then, W = nR logeV2/V1 [T1−T2] = Q = Q1-Q2
Carnot cycle efficiency
The efficiency of any heat engine (η) = W/Q1
Here, W = Q = Q1-Q2
= nR loge V2/V1 [T1−T2]Â
Putting these valves in the heat engine efficiency formula,
η = nR loge V2/V1 [T1−T2]/nRT1 loge V2/V1
η = [T1−T2]/T1 = Carnot cycle efficiency.
From the above relations,
η = [T1−T2]/T1 = [Q1-Q2]/Q1 = Carnot cycle efficiency.
Q2/Q1 = T2/T1
From this equation, we can say that the efficiency of the Carnot heat engine or the Carnot cycle efficiency depends upon the temperature of the source and sink,
it is independent of the nature of the working substance.
Carnot Cycle efficiency calculator
Why no heat engine can have an efficiency of 100% or 1?
The efficiency of a heat engine η = [T1−T2]/T1 = [Q1-Q2]/Q1
If you want to gain the efficiency equal to 1 or 100%,
then you must have T2 = 0 Kelvin and also, Q2 = 0
The T2 = 0 Kelvin, only when you have the value of heat Q2= 0
This means no loss of heat and all heat can be completely converted into work.
Which not possible, as it violates the second law of thermodynamics.
Hence, no Q2 = 0 and thus no T2 = 0, and no heat engine can have an efficiency of 1 or 100%.
Carnot theorem
The above relation for Carnot cycle efficiency is, Q2/Q1 = T2/T1Â
It can be seen from the relation, that heat engines operating in cycles between the same
two temperatures T1 and T2 can not have efficiency more than the Carnot reversible heat engine.
This is the Carnot theorem, that is, the efficiency of a Carnot reversible heat engine is maximum.
Another form of Carnot theorem in the same sense,
According to the Carnot theorem, the efficiency of all reversible heat engines operating between the same two temperatures is the same (equally efficient) and no irreversible heat engines operating between the same two temperatures can have efficiency more than the Carnot heat engine.Â
The refrigerator as a reversed Carnot cycle
As you know, the processes in the Carnot cycle are reversible.
Therefore, the Carnot cycle can be used as a reverse Carnot cycle.
After this, the reversed Carnot cycle worked as a refrigerator.
For a Carnot cycle, the Q1 heat is absorbed from the source at temperature T1 and Q2 heat is rejected to the sink at temperature T2.
The second law of thermodynamics not violated here.
But in the case of a refrigerator or reverse Carnot cycle,
the Q2 heat absorbed from the sink at temperature T2 and Q1 heat is rejected to the source at temperature T1.
This is a clear violation of the second law of thermodynamics.
As the heat can not transfer by itself from a lower temperature to a higher temperature, without any external agency.
Therefore in the case of a refrigerator, some external work is done to transfer heat from a low temp body to a high temp body.
For refrigerators, this work is performed by the compressor of the refrigerator by the use of electricity.
An interesting fact in the refrigerator
In the refrigerator, the amount of rejected heat Q1 is more than the amount of heat absorbed Q2.
This is because the amount of rejected heat Q1 is equal to the sum of work done W and heat absorbed Q2.
that is,  Q1 = W + Q2
Coefficient of Performance COP
The efficiency of the refrigerator is measured in terms of the Coefficient of performance.
The coefficient of performance is the ratio of the amount of heat absorbed from the sink to the work done by an external agency.
That is,  COP (k) = Q2/W
From the first law of thermodynamics, W = Q
Also, Q = Q1−Q2
k = Q2/Q1−Q2
Interesting fact!
The efficiency of all heat engines cannot be more than 100% but, the coefficient of performance can be 100% or more than 100%.
Example of Coefficient performance, in terms of Numerical question.
Question:
A Carnot’s refrigerator takes heat from water at 0°C and leaves it in the room. The temperature of the room is 27°C. 100 grams of water at 0°C is to be changed into ice at 0°C.
Find, how many calories of heat are discarded to the room? Also, find the Coefficient of performance? Given, one gram of heat = 80 calories.
Answer:
Her given that the temperature of water = 0°C = T2 = Sink’s temp.
T2 = 0°C + 273 K = 273 Kelvin
Here, Source temp = Room’s temp = T1 = 27°C, Given
T1 = 27°C + 273 K = 300 Kelvin,
Let Q2 and Q1 be the heat absorbed from the sink and heat rejected to the source.
Given, that Q2 = 100 gram of water = 100 × 80 calories = 8000 calories,
Applying carnot cycle efficiency equation,
Q2/Q1 = T2/T1Â
8000/Q1 = 273 K/300 K
Q1 = approximately 8791 calories.
The work is done by the compressor of the refrigerator
W = Q1−Q2 = 8791−8000 = 791
Then the coefficient of performance COP,
K = Q2/W = 8000/791 = 10.1
Also, Q1 = 8791 calories and Q2 = 8000 calories
From this example, we can say that the quantity of rejected heat by the refrigerator is much higher than the total quantity of heat absorbed from the sink.
Entropy and Carnot cycle
As you know dS = dQ/T  ⇒  dQ = TdS
The above relation is also the second law of thermodynamics, in fact, it is the mathematical formulations of the second law of thermodynamics.
In the Carnot, cycle entropy is used to draw a TS diagram to find Carnot cycle efficiency in terms of temp and entropy.
Also, the area of the TS diagram of the Carnot cycle is equal to the area of the PV diagram for the same Carnot cycle.
dQ = dW + dU  ⇒ Frist law of thermodynamics,
dQ = TdS      ⇒ Second law of thermodynamics,
dW + dU = TdSÂ Â
dU is zero as internal energy is a state function and change in internal energy for a reversible cycle is 0.
Hence mathematically,
∫PdV = ∫TdS
Carnot cycle TS digram
The above diagram represents a graph between temperature T and entropy S for a reversible Carnot cycle.
Like the PV diagram, the processes for a TS diagram of a complete Carnot cycle is similar, such as,
Line AB = Isothermal expansion, where the temperature T1 = Constant.
Line BC = Adiabatic expansion, where the Entropy S2 = Constant.
CD line = Isothermal compression, where the temperature T2 = Constant.
and line DA = Adiabatic compression, where the Entropy S1 = Constant.
Both the Lines AB (Isothermal expansion) and CD (Isothermal compression) are parallel to the entropy axis.
Here change in temperature ΔT = 0
The lines BC (Adiabatic expansion) and DA (Adiabatic compression) are parallel to the temperature axis.
Here change in entropy ΔS = 0
Now the quantity of heat absorbed by the source during the complete Carnot cycle = Q1
Q1 = +ΔS
For curve AB on the TS diagram.
The first process, which is reversible Isothermal expansion Q1 = TΔS
Q1 = T1(S2−S1)
For the curve BC on the TS diagram.  ⇒ (Second process, Adiabatic expansion)
ΔS = 0 (constant)
For the curve CD on the TS diagram.  ⇒ (Third process, Isothermal compression)
Q2 = −ΔS = −T2(S1−S2) = T2(S2−S1)
For the curve DA on the TS diagram   ⇒ (Fourth process, Adiabatic compression)
ΔS = 0 (constant)
Net work done during complete process W = W1 + W3 = Q1 − Q2
W = (T1−T2) (S2−S1)  ⇒ Enclosed Area of complete ABCDA Carnot cycle on the TS diagram.
Carnot cycle TS diagram efficiency.
The Carnot cycle efficiency in terms of TS diagram
The efficiency of a heat engine (η) = W/Q1
As, W = Q1−Q2
η = Q1−Q2/Q1
(T1−T2) (S2−S1)/T1(S2−S1) = T1T2/T1 = Carnot cycle efficiency.
Carnot cycle Conclusion
In the Carnot cycle, all processes are reversible but in nature, no process is perfectly reversible. So, the concept of the Carnot cycle is hard to digest.Â
The idea of the weightless or frictionless piston is also imaginary (hypothetical).Â
Hence, you can say that the setup of the Carnot heat engine Purely imaginary concept, and in real life, no heat engine exists.
That’s why the Carnot cycle is not used in power plants, automobile industries, etc.
Although the Carnot heat engine or Carnot cycle is completely imaginary,
but it established a maximum efficiency concept for all heat engines operating between the same T1(High) and T2(Low) temperatures.
That’s the End Of The Carnot heat engine!
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FAQ related to Carnot Cycle
There are few questions that are somehow co-relate to the Carnot Heat engine or if we say can be asked to know more about the Carnot Cycle.Â
1 What is the Carnot cycle in conventional and non-conventional?
According to us, after study complete the Carnot cycle we can say that (personal opinion) Carnot Cycle is non-conventional. As it broke our known-thermodynamic physics standards.Â
References
- https://www.grc.nasa.gov
- https://en.wikipedia.org
- https://chem.libretexts.org
- http://hyperphysics.phy
- https://www.sciencedirect.com
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